Benzoquinone Ligand-Enabled Ruthenium-Catalyzed Deaminative Coupling of 2-Aminoaryl Aldehydes and Ketones with Branched Amines for Regioselective Synthesis of Quinoline Derivatives | The Journal of Organic Chemistry https://t.co/axEftpTMwO
"The unique challenge which chemical synthesis provides for the creative imagination and the skilled hands ensures that it will endure as long as men write books, paint pictures, and fashion things which are beautiful, or practical, or both."
- R. B. Woodward-
Metalloradical Catalysis: General Approach for Controlling Reactivity and Selectivity of Homolytic Radical Reactions:
Mechanistic Insights and highlight their synthetic applications in organic transformations.
https://t.co/RIgRwwIuZ1
Meet metalloradical catalyst [Co(3,5-DitBu-Xu(2’-Naph)Phyrin)] that can readily activate diazomalonates at room temperature for radical cyclopropanation @ChemCatalysis https://t.co/RKA61FechE
Aa application to the unique catalytic intramolecular [1,3]-alkyl migration
Synthesis of Flavanone and Quinazolinone Derivatives from the Ruthenium-Catalyzed Deaminative Coupling Reaction of 2′-Hydroxyaryl Ketones and 2-Aminobenzamides with Simple Amines https://t.co/slam5OqnC0
Scope and Mechanism of the Redox-Active 1,2-Benzoquinone Enabled Ruthenium-Catalyzed Deaminative α-Alkylation of Ketones with Amines https://t.co/mkc3CMcFR0
“Why just NMR? –Because there is hardly another technique that is so informative for so many different types of applications, and because there is no other technique that provides so much fun.”
—Richard R. Ernst—
Really cool to meet Pandula, Daniel, Nicholas and James @jamc_n all at @MarquetteU as a part of my visit in the Chemistry dept there. Really smart bunch, we chatted about life after academia, research, plasmon... and twitter! #Milwaukee#VirtualSeminar#AcademicLifeUnderCOVID