Sasha Gazzari Jara

[Sasha Gazzari Jara @SGazzariJ]

Hello, @LatinXChem, glad to present my work "THEORETICAL STUDY OF Cu(I) CARBENOIDS AND THEIR ROLE IN C-H INSERTION REACTIONS", hope you like it ! #DTF #Catalysis #Carbenoid #Copper #Insertion #Activation #LatinXChem24 #LatinXChemComp #Comp032

[Sasha Gazzari Jara @SGazzariJ]

@Gore_Tarapaca
Estimados/as,

Neceisto solicitar información sobre registros de inmigrantes croatas en Tarapacá (1880-1920), me pueden ayudar?

Saludos

[Sasha Gazzari Jara @SGazzariJ]

@icorraluam @LatinXChem Hello Ines, thanks for the compliments.

There is indeed a direct correlation between the funcional groups and energy barriers, i.e. the highest barriers were found related with NH2 and the lowest barriers with CH3, which present different donor effects such as +M and +I

[Sasha Gazzari Jara @SGazzariJ]

Hello, @LatinXChem, glad to present my work "THEORETICAL STUDY OF Cu(I) CARBENOIDS AND THEIR ROLE IN C-H INSERTION REACTIONS", hope you like it ! #DTF #Catalysis #Carbenoid #Copper #Insertion #Activation #LatinXChem24 #LatinXChemComp #Comp032

[Sasha Gazzari Jara @SGazzariJ]

@icorraluam @LatinXChem another important relation was that the functionalization modified the electrophilic nature of the reactive C. This said the highest electrophilic C reflected a barrierless reaction and the opposite was observed for the lowest electrophilic C which presented the highest barrier

[Sasha Gazzari Jara @SGazzariJ]

@RS_Chemist @LatinXChem Bonsoir Rocio,

Thanks it means a lot to me that you like it, I calculated the barriers maintaining the functional with a TZ pseudo-potential and all electron, if I’m not wrong they were ~0.5 kcal.

[Sasha Gazzari Jara @SGazzariJ]

@kottidroguett @Pauta_cl @thenotco 😆