Tuczek Group

Coordination Chemistry for O2 and N2 Activation, SCO and on Surfaces. The account is administrated by group members.

[Tuczek Group @TuczekGroup]

@ChemEurJ The link doesn't seem to work, this one is functional:

https://t.co/e482A7Dfr6

[Tuczek Group @TuczekGroup]

A new publication @ChemEurJ! We reveal a mononuclear pathway for Cu-catalyzed phenol monooxygenation as an alternative to the classical dinuclear tyrosinase mechanism. DFT confirms the catalytic cycle, 18O-labeling MS/MS a new geminal diolate intermediate.
https://t.co/8dlGeFilqo

[Tuczek Group @TuczekGroup]

Check out our latest publication! A discrete molecular Cu₂O complex exhibits a methane C–H activation energy profile comparable to Cu/ZSM-5, providing new insights into methane-to-methanol conversion. #unikiel #Catalysis #Methane #copperenzymes #acsomega

https://t.co/5pUJ7a5eQd

[Tuczek Group @TuczekGroup]

Read our new review @ChemPhysChem about the pentaPod concept, uniting tridentate and tripodal P donor systems for Mo and W complexes for N₂-to-NH₃ conversion. Recent studies and mechanistic insights reveal how the P5Me/P5Pln systems affect reactivity
https://t.co/TuHQhQj44Y

[Tuczek Group @TuczekGroup]

Tobias Engesser and Alexander Koch from @kieluni were visiting @UBO_UnivBrest lately to do exciting mass spectrometry for oxygen activation.
This is part of @SeaEuAlliance and our cooperation with Brest researchers Prof. Antony Memboeuf and Dr. Nicolas Le Poul.
#unikiel #SEAEU

[Tuczek Group @TuczekGroup]

Congratulations to Prof. Felix Tuczek on receiving the 35th EGON-WIBERG-VORLESUNG of the MÜNCHENER CHEMISCHE GESELLSCHAFT E.V. (GDCh-Ortsverband München) for his contributions in bioinorganic, coordination, SCO and surface chemistry! 🏅

Lecture: 10 July 5 pm @LMU_Muenchen

[Tuczek Group @TuczekGroup]

Read our new paper in @daltontrans ! Inspired by famous [Fe(H2B(pz)2)2(bipy)], we bridged two [Fe(H2B(pz)2)2] units with dinucleating ligands, creating dinuclear iron(II) compounds with intriguing spin-crossover properties! #SpinCrossover #LIESST #unikiel

https://t.co/PQ2tbMwFqN

[Tuczek Group @TuczekGroup]

Publication in @ChemCatChem! Influence of denticity, chain length and N-alkylation of N-donor based ligands on the catalytic activity for Cu catalyzed monooxygenation of phenols and the CuAAC reaction was investigated! #catalysis #bioinorganic #tyrosinase

https://t.co/8JzpAXjrrl

[Tuczek Group @TuczekGroup]

Check out our two new papers in @ChemEurJ ! Metal-organic complexes adsorbed on metallic surfaces as potential single-site catalysts, bridging the gap between homogeneous and heterogeneous catalysis #SurfaceScience
https://t.co/mcFwbydGD2
https://t.co/Jsp38KIrWz

[Tuczek Group @TuczekGroup]

Publication in @EurJIC! Molybdenum tricarbonyl complexes [Mo(CO)3PNPhPR] with various PNPhPR ligands (R=Ph, Et, Cyp, iPr, Cy), all show a facial coordination mode! Phenyl group of PNPhP function kinetically hinders isomerization, unlike in PNHP analogues.
https://t.co/1ruMbVe1Gq

[Tuczek Group @TuczekGroup]

Our latest publication in @ChemicalScience! Vacuum-evaporable complex [Fe(pypypyr)2] as bulk material & thin film, staying low-spin up to 510 K and the light-induced high-spin state lasts for hours instead of ns. #LIESST #spincrossover #surfacechemistry
https://t.co/YysfpPoLbZ

[Tuczek Group @TuczekGroup]

Exciting news! Our latest paper on Cu complexes supported by new Ltrz ligands as catalysts for monophenol to o-quinone conversion is now available in @Orgmet_ACS. The ligands lead to 20-100% higher activities than simple Cu salts. #bioinorganic #tyrosinase
https://t.co/n9J1rntivb

[Tuczek Group @TuczekGroup]

Discover the fascinating world of nitrogen fixation with this insightful review! Learn about the structure and function of nitrogenase and catalytically active small-molecule models, and uncover common trends in N2-to-NH3 conversion. #nitrogenfixation
https://t.co/9J3EElbS7r

[Tuczek Group @TuczekGroup]

Check out our latest publication in @ChemEurJ! We investigated the difference in catalytic activity between homogeneous Mo and W catalysts for N2 fixation and the competitive hydrogen evolution.
#unikiel #inorgchem #chemistry #n2fixation

https://t.co/4uTrPn3Di3

[Tuczek Group @TuczekGroup]

Clara Trommer giving an inspiring talk about spin crossover compounds on the 21st Conference on Inorganic Chemistry of the GDCh (Wöhler-Tagung 2022) in Marburg!
#caukiel #gdch_aktuell #InorganicChemistryConference2022 #woehler @JungeWohler #spincrossover

[Tuczek Group @TuczekGroup]

Congratulations to Rebecca Schneider on winning the prize for the best presentation on the KCT 2022 @UniJena!
We also congratulate Jean-Marc Mörsdorf (middle) from the Ballmann group on his award and thank Prof. Plass (left) and his group for hosting and organization!
#caukiel

[Tuczek Group @TuczekGroup]

Küpra Yildiz presenting her latest amazing results about surface deposition at the Coordination Chemistry Meeting 2022 @UniJena (KCT 2022)!
https://t.co/3MW96krnnF
#unijena #unikiel #coordinationchemistry #inorgchem

[Tuczek Group @TuczekGroup]

@chalkley_talk @PGarridoBarros @JDerosaChem @Nature Really nice work and impressive results! 👍

[Tuczek Group @TuczekGroup]

We did it again! Tuczek Group won the Chemist Cup 2022. Congratulations to the team! 🏆⚽️

[Tuczek Group @TuczekGroup]

Check out our latest publication in @angew_chem! A weakly coordinating anion significantly improved the catalytic tyrosinase-like activity, leading to the highest activity so far! #unikiel #catalysis #bioinorganic #tyrosinase

https://t.co/aQJXS5ovlU