@Daffytha@LatinXChem@aguilarjuliox Por lo que el sistemas es técnicamente reversible, pero la relación de corrientes de pico es distinto a la unidad, probablemente porque el mecanismo de reacción sea más complicado que lo que estamos proponiendo.
@Daffytha@LatinXChem@aguilarjuliox Esta propuesta es una primera aproximación con la que intentamos describir al sistema. La diferencia de potencial entre picos para pH 1.5 a 2.5 (líneas Roja, verde y azul) es de 70, 60 y 60 mV, respectivamente.
@criskalinke@LatinXChem@aguilarjuliox As we can see, the lowest value is obtained in the unmodified electrode, and the increase in this parameter as a function of oxidation time could suggest surface functionalization (ferro/ferri experiences some electrostatic repulsion by the surface)
@criskalinke@LatinXChem@aguilarjuliox Sure, Rct depends on the reaction in which we are estimating it. ferro/ferri is a charged species, so surface charge has an effect on the Rct value.
@Daffytha@LatinXChem@aguilarjuliox Desafortunadamente no conocemos le mecanismo, ya que para determinar el grupo funcional o grupos funcionales que estan reaccionando requerimos de espectroscopias que nos ayuden a caracterizar los.
@Daffytha@LatinXChem@aguilarjuliox De forma que al graficar potencial de media onda vs pH puede obtener la relación de protones y electrones que se intercambian.
@criskalinke@LatinXChem@aguilarjuliox The electrode oxidized at 25 cycles showed a higher current in the experiments in Figure 4 and that is why it was used.
@criskalinke@LatinXChem@aguilarjuliox The measurement cannot be made on an bare electrode because initially the anodic barrier is given by the oxidation of the electrode at +1 V. Once oxidized it moves to higher values, which allows the measurement to be carried out.
@criskalinke@LatinXChem@aguilarjuliox "Activation" means "an improvement of electrocatalytic properties" as a reduce of charge transfer resistance. But in this case we found that the oxidation can be carry out in certian conditions to reduce the Rct.
The organizers and judges of the #LXChemComp category, together @digital_rsc of the @RoySocChem, award the prize for best poster to @beatrizcastrogm of @CIQUAEM for her poster entitled "Estructura y dinámica dependientes del espín: cúmulos de oxígeno molecular"
The organizers and judges of the #LXChemComp category with @SuntheticsML, award the second best poster to @Val_BonillaGo of @UNALOficial for her poster entitled "Energy transfer in light-harvesting macromolecules"