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A true synthetic tour de force work by @ChemXin and team, showing how one can rapidly build up topologically complex molecules with boron cluster templates: B−H oxidation enables modular synthesis of vicinally trifunctionalized boron-rich clusters: Chem https://t.co/CQ7oDtwmjE
Boron cluster with boron-centered redox activity?Check.
Same cluster with boron-centered basic sites that can be reversibly protonated? Check.
With these two unique properties established in the same system, we present the first manifestation of boron-centered PCET reactivity. For more, check out this preprint: https://t.co/JEWqs8IeH3
Work led by Varun Tej in a collaboration with @ChemXin, Hannah Shafaat and their amazing teams!
#EurJOC Pd-Catalyzed Vicinal Difunctionalization of Carboranes with Benzoxazoles, Indoles, and Anilines (Xin Mu and co-workers) @ChemXin • https://t.co/8WI15wjI57
Excellent work led by our group alum Kent Kirlikovali and @Farhomies team. Clearly shows that dicarbollides are under-recognized/utilized ligands in the actinide community with a lot of potential and that community should be taking notes.
What an incredible chance to dive into the thrilling world of boron chemistry and catch up with friends at BORAM18 at UCLA! Huge thanks to Alex for the invitation!
Annoucment at the #BORAM18 conference today. Save the date 🗓. The next Imeboron symposium (IMEboron 18) will be organized by Prof @makoto_B in September 2026 in Tokyo.
Great collaboration with Alex @organomimetic and we’ve learned a lot from this work! Hopefully we could forge more powerful toolbox to achieve complex manipulations of carboranes in the future!
Check out our work that just appeared in @J_A_C_S on the development of the fastest organometallic Cys bioconjugation reagents: https://t.co/wuBKmpsSm3. Shout out to many @uclachem collaborators on this project including: @group_maynard and @houk1000.