Chemistry PhD candidate in @Vy_Dong_Group at UCI. NSF-GRFP fellow. HMC '19. Enjoys long walks on the beach (with my dog). Views are my own. #BLM She/her/hers.
Had so much fun at the Natural Products and Bioactive Molecules GRS! Heard about some amazing science and got to share some of my own 😁 coincidentally there’s a Slocumb Hall here at the campus! Looking forward to the GRC!
Thanks @mramirez9409 for spending the day @UCIChemistry as the inaugural speaker in our Future Leaders Seminar—here’s Dr Rameriz with other future leaders 😀 @lissathechemist
@Stilbene27 Thanks Calvin! Glad you enjoyed it 😁 unfortunately the nose hasn’t totally been given a break but hopefully our next smelly article is out soon!
What's MORE stinky and LESS fun than thiols 🦨?! Congrats @HannahSlocumb5@NieShaozhen and Xiaohui on first asymmetric coupling of selenols and styrenes: https://t.co/MuI7lZQ4X6
So awesome working with Calvin this summer! I was constantly impressed with his chemistry knowledge and enthusiasm, and sad that he already has to go back to school! Excited to see where he goes from here, I know he’s going to do great things 😁
It was an honor to work with @HannahSlocumb5 this summer in the @Vy_Dong_Group! She’s super smart, funny and hardworking. I appreciate all of the advice she gave me during my time at UCI, and I hope and know she’ll earn that Ph.D. very soon! Also, I know that I suck at posing.
Very excited and honored to have been chosen to represent UC at the Lindau Nobel conference! Big thanks to @Vy_Dong_Group for all the help and support getting to this point 😊
@ThuyPham0815@Vy_Dong_Group Thanks Thuy! I haven’t tried one with R2=Cl, but I imagine it’d work similarly since Cl-substituted pyrazoles do work in our reaction. For ja/ka, the oxygen of the furan could competitively bind to the Pd center and promote off-cycle complexes, decreasing reactivity/yield.
Check out my #RSCPoster on our enantioselective addition of pyrazoles to dienes! A fun project in @Vy_Dong_Group lab published last year in ACIE https://t.co/R8DIwXdNni #RSCOrg
@basker25071980@Vy_Dong_Group Thank you! The 1,2-selectivity is likely due to a higher preference for the pi allyl to put the pi conjugation next to the arene ring (1,4-addition is the major regioisomer for the cyclohexane substrate!). It’s also possible that sterics affects the pyrazole attack too.
@chemistfromIND@Vy_Dong_Group Thank you! I’m not totally sure as to the reason, but my immediate thought is that the oxygen of the furan could competitively bind to the Pd center and promote off-cycle complexes, decreasing reactivity/yield.
Super excited to share my work with @NieShaozhen and Alexander Lu on the enantioselective hydrothiolation of cyclopropenes! Feel free to check out the paper in JACS or ask any questions for more information. #RSCPoster#RSCOrg https://t.co/pkkjt1HXo0