Ashish

Postdoc @NUChemistry (Tobin Marks Group) PhD @RutgersChem ( @Goldman_Group) MS Chemistry @IITKanpur

[Ashish @Parihar_chemist]

Check this preprint which covers a big chunk of my doctoral work here at @Goldman_Group . A big thanks to Faraj, @alansgoldman for completing this story. And a huge shoutout to @iridium_tea for fruitful discussions on cationic pincer iridium chemistry.

[Goldman Group @Goldman_Group]

🚨Check out this new preprint https://t.co/2MELMk5N9x by @Parihar_chemist of @Goldman_Group at @RutgersChem reporting (iPrPCP)IrH+ for dehydrogenation, hydrogenation & H/D exchange with unusual selectivity. Proceeding via a novel mechanism of C-H addition & beta-H elimination.

[Ashish @Parihar_chemist]

I am thrilled to share that the final version of our work is now published in @ACSPublications JACS Au https://t.co/z7eiodTRBf @Goldman_Group @RutgersChem

[Ashish @Parihar_chemist]

🚨Check out this preprint from @Goldman_Group on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental oxidative addition/reductive elimination steps.
https://t.co/7oQxhgmXnl

[Ashish @Parihar_chemist]

🚨Check out this preprint from @Goldman_Group on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental oxidative addition/reductive elimination steps.
https://t.co/7oQxhgmXnl

[Alan Goldman @alansgoldman]

Proud of this work with collaborator (and former group member) Santanu Malakar @random_chemist, lead author Souvik Mandal @souvik_mndl, and team including Samuel Zhou, Rachel Allen, Faraj Hasanayn, Alex Miller, Quinton Bruch - see paper for all authors...!

[Ashish @Parihar_chemist]

@nitinsharma_07 @angew_chem @Dethe_IITKanpur @sakshijuyal_14 @Chemistry_IITK Great work! Congratulations to the team.

[Akshai Kumar @AkshaiK55372786]

Kudos to @im_vsaini for a detailed work on Pincer–Ruthenium Catalyzed Selective α‐Alkylation of Nitriles - Vikas - ChemCatChem - Wiley Online Library https://t.co/uTxhkmy33x
@IITGChem
@IITGuwahati
@CfN_IITG
@ANRFIndia
@ChemEurope

[Alan Goldman @alansgoldman]

@Goldman_Group @Parihar_chemist @RutgersChem Several bizarre aspects of this system include a huge preference for both dehydrogenation AND hydrogenation of 5, 7 and 8 membered rings vs. 6-membered. Much gratitude (and possible co-authorship?) to any organic-savvy chemist who can find a good application for this selectivity!

[Alan Goldman @alansgoldman]

Kudos to @Parihar_chemist for an awesome study revealing a novel mode of C-H activation/ dehydrogenation/hydrogenation by a protonated pincer Ir catalyst

[Goldman Group @Goldman_Group]

Congratulations to @Goldman_Group member @das_soumyadipa for her successful dissertation defense. She is headed to @pfizer for her next journey 🎉🎁

[Ashish @Parihar_chemist]

Congratulations to my mentor of grad school @random_chemist who will be starting as an Assistant Professor. He introduced me to the field of organometallic chemistry (experimental and computational).
PS: His students will be lucky to have a guide like him.

[Goldberg Lab @GoldbergLabPenn]

Celebrated our postdoc @random_chemist Santanu's last day with a chinatown lunch and boba 🧋 outing! Santanu has accepted a position as an Assistant Professor at Rutgers University-Camden Congratulations Santanu!!!

#summer2024

[Ashish @Parihar_chemist]

Attending #ACSFall2024 ? Do check out @SohamC1997 talk on C-H activation using pincer ruthenium complexes. Congratulations🍾🎈🎊

[Goldman Group @Goldman_Group]

Congratulations to @Goldman_Group member @SohamC1997 for receiving the ACS CATL-CHEMCATBIO Graduate Student Travel Award @ACSCATLDivision . Also, do check out @SohamC1997 giving a talk at #ACSFall2024 in Bluebird Ballroom 3G (details attached)

[Belvin Thomas @ThomasBelvin]

Excited to share a new paper published in @JMaterChem
where we show that Bismuth can enhance the electrocatalytic activity of Cobalt oxide towards acidic oxygen evolution reaction (OER) and Bismuth can also serve as an active site.
https://t.co/i8cMpqf2hz

[Rick Remsing @rcremsing]

Now published in @ACSEarthSpace !

Check out @atulCthakur's latest on plastic crystals on Titan - this one might still be rotating at very low temperatures 🥶🪐

https://t.co/M1wesgMyIC

[Goldman Group @Goldman_Group]

@Goldman_Group lab members at this years GRC Organometallics in Rhode Island.

[Ken Lo @bhkenlo]

Kinetic Isotope Effects and the Mechanism of CO2 Insertion into the Metal-Hydride Bond of fac-(bpy)Re(CO)3H | Inorganic Chemistry https://t.co/N3eR0TdcJZ Hasanayn and co-workers @InorgChem #rhenium #KIE #CO2 #insertion #metal_hydride #TS2

[Rick Remsing @rcremsing]

New preprint from @atulCthakur on another Titan cryomineral in a plastic phase

Weak interactions = nearly free rotation and disorder persisting to very low temperatures

https://t.co/MLjBb1kOY5

[Tariq ⌬ @iridium_tea]

Congratulations @Ashish24934821! Good science here: recognizing something new and unexpected, and teaching us why it's interesting.

[Goldman Group @Goldman_Group]

A major team effort (Rutgers, UNC and AUB)! Synthesis and multi-pronged study of a new Mo catalyst for N2 to NH3 yields deeper insight into the workings of such catalysts. Congrats team leads @random_chemist @souvik_mndl @SamuelZhou5 https://t.co/L7YbMQuoh2


[Goldman Group @Goldman_Group]

The final version of this article is out now in @Orgmet_ACS. Do check this out https://t.co/5kaMpuX7mt
Congratulations @Ashish24934821

[Vishav Sharma @vishavsharma_]

Thiamin Biosynthesis!! Radical SAM Enzyme!! Remarkably Complex Chemistry!!
Check out our work on the mechanistic enzymology of the ThiC-catalyzed reaction in bacterial thiamin biosynthesis in @ACSCentSci. It was a great team effort. (1/3)
https://t.co/8Ah7mQmowT