Very happy to share this work just published in
@AdvSynthCatal! A simple reaction system enables site-selective deoxygenation of benzyl alcohol derivatives without pre-functionalization.
https://t.co/L5DIQUomoO
A conceptually novel asymmetric synthesis, termed “reflexive chirality transfer (RCT)”, is out in
@J_A_C_S! The 1,3-dipolar cycloaddition of amino acid Schiff bases proceeds with "preserved chirality" despite temporarily losing chirality at the α-carbon.
https://t.co/Yfho9QcI39
Aliphatic amines can be used as a hydrogen source in alkyne reduction under mild photocatalytic conditions. It was started when exploring byproducts in another project and taught us many lessons. Congrats to the team 🎉
https://t.co/s7lHdWqMqO
Conceptually new asymmetric transformation—Reflexive Chirality Transfer (RCT)— appeared in @ChemRxiv (https://t.co/LNFljXeLSO).
1,3-Dipolar cycloaddition of amino acid Schiff bases proceeds with "preserving chirality" despite the once loss of the chirality at the α-carbon.
Mr. Furuki received the Poster Award at Chirality2024 held in Kyoto. https://t.co/vk1NUOqcOP
Congratulations!
"Reflexive Chirality Transfer: Chiral Ligand-Free Catalytic Enantioselective 1,3-Dipolar Cycloaddition of Amino Acid Schiff Base"
We will join Chirality2024 @ Kyoto. Mr.Furuki has a poster presentation about conceptually new catalytic asymmetric reactions at PB63. "Reflexive Chirality Transfer: Chiral Ligand-Free Catalytic Enantioselective 1,3-Dipolar Cycloaddition of Amino Acid Schiff Base"
We'll join @Icomc2024 held in Agra! Our group has one invited presentation talked by Prof. Sato, and three poster presentations by Mr. Miyamoto, Mr. Yagi, and Mr. Abe.
Day 4 15:15 – 15:40, Room 3 (page # 202)
Transition Metal-Catalyzed Reductive Cyclization via Metallacycle Intermediates Without Use of Metal Reductants
○ Yoshihiro Sato
(ref. 10.1021/acs.orglett.3c00524)
Very happy to share our latest work on "fluorinated" organometallic chemistry!
Zn/F Carbenoids: Preparation, Structures, Stability, and Application to Nucleophilic Monofluoroalkylation – now published in Org. Chem. Front.
https://t.co/gERMbeVggj
Delighted to share our latest publication in @AdvSynthCatal. The cascade reaction of ynamides with propargyl thiols by Au(I) catalysis enables one-pot synthesis of 2-aminothiophenes. https://t.co/1MrCLzmYBa