TimBruckhoff

PhD Student, Gade Lab, @UniHeidelberg

[Maximilian Roca Jungfer @RocaJungfer]

Finally: structurally confirmed Tc alkyne complexes - just in early view @angew_chem. https://t.co/tFLYI906Hb
#Organometallics #Radiochemistry #Technetium #99mTc #Alkyne
Big thanks to the whole team and supporters (KIT, @fubcp, @UniHeidelberg, @ChariteBerlin, @chemieverband)!

[TimBruckhoff @TimBruckhoff]

Do you know how to control Ni(I) or Pd(I) metal-metal bonds? Is ligand flexibility really problematic for metalloradical accessibility and stability? I'm excited to share some answers in our paper, just published. I hope you enjoy the read and perhaps find it inspiring:

[Angewandte Chemie @angew_chem]

Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals (Lutz H. Gade and co-workers) #AngewandteVIP • https://t.co/8N8wX6gqw3

[Angewandte Chemie @angew_chem]

Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals (Lutz H. Gade and co-workers) #AngewandteVIP • https://t.co/8N8wX6gqw3

[TimBruckhoff @TimBruckhoff]

@TakebayashiS Great fundamental work! I found your paper after observing reversible bond homolysis in NMR myself. (People can actually find it by simply searching for "bond homolysis NMR" in Google.)

[Angewandte Chemie @angew_chem]

Radicalizing CO by Mononuclear Palladium(I) (Lutz H. Gade and co-workers) #openaccess @TimBruckhoff https://t.co/IsfeNAnNxp

[Hohloch Lab @HohlochL]

#KCT2024 @uniinnsbruck is over. We (⁦@HohlochL⁩, @DielmannGroup, H. Schwartz, G. Heymann) thank every participant and all sponsors for making this conference an incredible experience. We are looking forward to see you in 2025 ⁦@uni_muenster⁩ ⁦⁦@MuellerChem⁩

[Ken Lo @bhkenlo]

To Split or Not to Split: [AsCCAs]-Coordinated Mo, W, and Re Complexes and Their Reactivity toward Molecular Dinitrogen | Inorganic Chemistry https://t.co/yDuoo7NHaS Ballmann and co-workers @InorgChem #molybdenum #tungsten #rhenium #halides #N2

[Organometallics @Orgmet_ACS]

Another special day for @Orgmet_ACS, we present "Early Transition Metals in Organometallic Chemistry" (Part 1!) illustrating the rich and diverse chemistry of electropositive metals, https://t.co/nonw4LxgDp. Thanks to @beweries_LIKAT, T. K. Panda, @CortnieRoberts
, H.Tsurugi.

[Hansmann Lab @MMHansmann_chem]

Congratulations to Justus and Patrick for their work published at @angew_chem ! We present a simple strategy to acess a fundamental new R2C=C=N2 class. How many new and stable CHN compounds are still out there? https://t.co/jBDHc4FJc8

[TimBruckhoff @TimBruckhoff]

I am very happy to see our investigations on an open-shell tantalum alkylidene finally available online.

So if you are interested in "exotic organometallic complexes", it might be worth checking out:

https://t.co/Wba0C0iHvx