Deepak Ranolia

PhD Scholar
Technion Israel Institute of Technology, Haifa, Israel

[Mark Gandelman @MarkGandelman]

Happy to share our latest Angewandte Chemie paper, in which we report a new class of nitrogen-based ligands that exhibit L-, X-, and for the first time, Z-type coordination, enabling an interesting concept of redox-by-coordination.

https://t.co/bJSfnkq91V

[Mark Gandelman @MarkGandelman]

Chemoselective catalytic C=O reduction of conjugated enones has been challenging and largely the domain of metal-based catalysts. We show that N-Heterocyclic Nitrenium can serve as an efficient organocatalyst for this transformation. The mechanism is quite complex :)

[J. Am. Chem. Soc. @J_A_C_S]

Organocatalytic Deoxygenative Reduction of α,β-Unsaturated Ketones | Journal of the American Chemical Society https://t.co/nF6qF0yBLj

[Chemistry News @ChemistryNews]

Triazenolysis of alkenes as an aza version of ozonolysis https://t.co/98UpG3XQ9b

[Mark Gandelman @MarkGandelman]

We developed a novel reaction that enables a direct synthesis of amines from olefins via C=C bond cleavage. This process which we termed Triazenolysis represents an aza-version of ozonolysis reaction.
Congrats to all involved
@NatureChemistry @TechnionLive
https://t.co/oIDb8H93JK

[Mark Gandelman Group @mark_gandelman]

We are happy to share our latest paper in @Orgmet_ACS about stereoselective catalytic synthesis of dienyl esters from simple alkynes and carboxylic acids. A new cooperative catalyst is presented. Congratulations to the team. @MarkGandelman https://t.co/avMB8iqI6d

[Mark Gandelman Group @mark_gandelman]

Congratulations to our Dr. Chen who successfully defended his PhD exam today! Zeqing worked on "asymmetric catalytic synthesis of fluoroalkanes." Wishing you an exciting journey ahead in your post-PhD adventures!
@MarkGandelman

[Mark Gandelman Group @mark_gandelman]

In these hard days for us, some nice news: our recent work in @ChemicalScience about an employment of the nitrenium ions in electrophilic amination made it to the cover. Congratulations @chemistrykuldee @Idan_Avigdori @MarkGandelman.
Link for the paper. https://t.co/N7CUCW4fQh

[Chemical Science @ChemicalScience]

Nitrenium ions as new versatile reagents for electrophilic amination

Check out Mark Gandelman et al.'s #ChemSciCovers🎨 article today! 😍⬇
https://t.co/Z8HheYQQ3G

[Organic Chemistry Portal @organic_portal]

https://t.co/JkInU9nLQC
Tetraaryl-1,2,3-triazolium salts catalyze a facile hydrosilylation-deoxygenation of ketones, aldehydes, acetals, alcohols, ethers, and silyl ethers

[Mark Gandelman Group @mark_gandelman]

Check out our latest publication regarding the use of nitrenium ions as versatile reagents for electrophilic amination.
Congratulations to the team. @chemistrykuldee
@Idan_Avigdori
@MarkGandelman
#nitrenium #nitrogenlewisacids
https://t.co/N7CUCW3I0J

[Mark Gandelman Group @mark_gandelman]

From lab to memories, we part ways. Grateful for shared laughter, experiments, and unwavering support. Farewell, dear @chemistrykuldee @Idan_Avigdori. Our paths diverge, but our friendship remains eternal. Best wishes for your remarkable future endeavors.

[Angewandte Chemie @angew_chem]

Intramolecular Ynamide-Benzyne (3+2) Cycloadditions (Hiroshi Takikawa and co-workers) @KUGousei @univkyoto https://t.co/OgSGYVuj7B

[Deepak Ranolia @deepakranolia11]

The organic chemistry portal @organic_portal has highlighted our study as the relevant and important deoxygenation chemistry in recent literature. https://t.co/kuQak5LVtq
@chemistrykuldee @Idan_Avigdori @MarkGandelman @mark_gandelman

[Organic Chemistry Portal @organic_portal]

https://t.co/5vyE6aXkMs
Deoxygenations - An overview of some recently published methods

[Mark Gandelman Group @mark_gandelman]

Want to see a N-H bond that can be a donor of H+, H-, or H-radical as well as to learn about the isolation and crystallization of stable triazinyl radicals, here is our latest article.
@MarkGandelman @J_A_C_S
https://t.co/UpP8s6cHtT

[Mark Gandelman Group @mark_gandelman]

Invited article published.
Dedicated to Prof. Stephan Douglas @FLPchemist on the occasion of his 70th birthday.
"Nitrenium salts in Intramolecular Lewis pairs."
Congratulations to the team 👏.
@chemistrykuldee @Idan_Avigdori @MarkGandelman #OpenAccess https://t.co/Yody6ucCxc

[Mark Gandelman Group @mark_gandelman]

Strong bond activation Conference at Ein gedi hotel at Dead sea. With @MarkGandelman @chemistrykuldee @Idan_Avigdori

[The Nobel Prize @NobelPrize]

BREAKING NEWS:
The Royal Swedish Academy of Sciences has decided to award the 2022 #NobelPrize in Chemistry to Carolyn R. Bertozzi, Morten Meldal and K. Barry Sharpless “for the development of click chemistry and bioorthogonal chemistry.”

[Mark Gandelman Group @mark_gandelman]

#ICS2022 #ICSMeeting