Dilman Lab

Prof. Alexander Dilman's group at the Zelinsky Institute. Our research is focused on organofluorine chemistry and photocatalysis.

[Dilman Lab @DilmanLab]

Pyridine meets difluorocarbene. Our paper on synthesis of difluoroalkylated hetarenes is finally online! Please check it out in @JOC_OL

#fluorine #carbene #heterocycles

https://t.co/ua9clTeLzN

[Adv. Synth. & Catal. @AdvSynthCatal]

Just accepted Update by Alexander D. Dilman and co-authors: Generation of Alkyl #Radicals from #Thiols via #Zinc Thiolates: Application for the Synthesis of gem‐Difluorostyrenes https://t.co/3cILUQyE1n

[Adv. Synth. & Catal. @AdvSynthCatal]

Just accepted Update by Alexander D. Dilman and co-authors: #Photoredox #Fluoroalkylation of #Hydrazones in Neutral and #Reductive Modes https://t.co/66shvNloFe

[ChemPhotoChem @ChemPhotoChem]

Visible-light-promoted reversible sulfide/iodide exchange in fluoroalkyl sulfides enabled by electron donor-acceptor complex formation (van der Worp, Kosobokov, Dilman @DilmanLab) https://t.co/GT6E9wDl4K

[Chao Li Lab @LabChao]

After having thought about the dehydoxylative cross-coupling for years (since I was a postdoc in Baran Lab @BaranLabReads), we finally figured out an expedient method @J_A_C_S: https://t.co/OJ7qNjx7NG

[Angewandte Chemie @angew_chem]

Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds by @DilmanLab https://t.co/UotUldOqxB

[Dilman Lab @DilmanLab]

@andrei_yudin @A_Aspuru_Guzik @SeferosGroup Great work, Andrei! Novel structures, and readily accessible!

[Andrei Yudin @andrei_yudin]

Boramidines are new motifs with potential in many areas. Finding small heterocycles that are stable to water and a wide range of solvents, yet have somehow eluded synthesis, is interesting. @A_Aspuru_Guzik @SeferosGroup https://t.co/UxQlY97CHq

[Au Chem @gold_chem]

Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers @DilmanLab @BeilsteinInst: https://t.co/FurTcLGYqr

[Boron-Chem-Research @Boron_Chemistry]

ortho-Dialkylamino Arylboranes as Efficient Reagents for Difluorocarbene Trapping : https://t.co/BdrlKhHDuC

[Angewandte Chemie @angew_chem]

Trapping of Difluorocarbene by Frustrated Lewis Pairs (Dilman) https://t.co/Nrixfy2iQX

[Dilman Lab @DilmanLab]

Thank you for highlighting our work.

[Boron-Chem-Research @Boron_Chemistry]

Trapping of Difluorocarbene by Frustrated Lewis Pairs (@DilmanLab): https://t.co/b3QhJkvWST

[J. Am. Chem. Soc. @J_A_C_S]

Acetylene trimerization reported by Berthelot and Zelinsky was finally unveiled. The mistery of self-promoted carbocatalytic synthesis of benzene. @AnanikovLab https://t.co/adxNRRaZUP

[nagib lab @nagiblab]

Double (vicinal) C-H functionalization of alcohols!

Check out this cool “reversed” radical/polar crossover mechanism @J_A_C_S by Allen, Raymond, & Ethan!

https://t.co/KWFLhhUs3W

[Dilman Lab @DilmanLab]

Our latest paper "Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation" is now online
@JOC_OL

#visiblelight #catalysis #radicals

https://t.co/BkxdJzaECh

[Glorius Group @GloriusGroup]

Seeing double👀👀 after new year's revelry🎆? Then please check out our latest publication on dual Cr-photoredox catalysis to access 1,2-amino alcohols, just accepted in @J_A_C_S.
#chromium #photoredox #catalysis #aminoalcohols

https://t.co/g7Fzk9oTLo

[Dilman Lab @DilmanLab]

Check out our recent @JOC_OL paper.

https://t.co/Zl3ZigzY43

#photoredox #radical #fluorine

[Cornellab @CornellaLab]

Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 https://t.co/AhXscyQzLU

[Dilman Lab @DilmanLab]

Check out our new paper – now published in @ChemicalScience !

https://t.co/nL1EWhBKGB

#photoredox #radical #fluorine

[Angewandte Chemie @angew_chem]

Photoredox Catalytic alpha-Alkoxypentafluorosulfanylation of alpha-methyl- and alpha-phenylstyrene using SF6 (Wagenknecht) https://t.co/uYCNLpAxOX