Anticancer Activity of Imidazolyl Gold(I/III) Compounds in Non-Small Cell Lung Cancer Cell Lines https://t.co/21W3brPCL4 #mdpipharmaceuticals via @MDPIOpenAccess
We demonstrate CTC@CTC’ stacked pairs w intertrimer coordinate-covalent bonding (d(Ag–Au) 2.868(2) Å; ΔE > 50 kcal/mol, an order of magnitude > aurophilic bonding). CTC@CTC’ pairs remain intact/strongly-bound even in solution (Keq > 10^5 L/mol via NMR/UV-vis) & gas phase (MS).
A Broadened Class of Donor‐Acceptor Stacked Macrometallacyclic Adducts of Different Coinage Metals - Lu - Chemistry – A European Journal - Wiley Online Library https://t.co/fdrFV1bC6s