Happy to share our latest work on photexcited nitroarenes just published in @NatureChemistry. Check out how we turn them into complex azepanes in just two steps. https://t.co/LyorT1MdZf
Our work on "Construction of Unsymmetrical Heterobiaryls via Cp*Rh(III)-Catalysed C-H/C-H Coupling of Heteroarenesโ is online now. Mechanistic studies support the oxidation of Rh(III) to Rh(IV) before reductive elimination.
https://t.co/Xo0YVYUHQm
Synthesis of 1,3-Dienes via Ligand-Enabled Sequential Dehydrogenation of Aliphatic Acids | Journal of the American Chemical Society https://t.co/v4M3Vdk94U
Distance & geometry is emerging as key principle for ligand design to lower prohibitive TS. Molecular editing of saturated rings is made possible. Nature asap: https://t.co/UKSb6bqZl5. Licensed to the newly founded ArCHitect Therapeutics.