Top Tweets for #Mesoionic
Tetrazolylidene-Stabilized Gold(I) Complexes: Synthesis and Evaluation of Anticancer Activity In Vitro | Inorganic Chemistry https://t.co/8F2cZyOLJI Casini, Kühn, and co-workers @InorgChem #gold #tetrazolylidene #mesoionic #cytotoxicity
Unusual “mesoionic” N^S biscyclometallated iridium(iii) polypyridine complexes as photosensitisers for photodynamic therapy and type II immunogenic cell death inducers - Chemical Science
https://t.co/gWBeskKFTU @bhkenlo @ChemicalScience @CityUChem #mesoionic #ROS #ER #TypeII #ICD
The Interplay of Cyclometalated-Ir and Mesoionic Imines: Stoichiometric and Catalytic Reactivities | Inorganic Chemistry https://t.co/EqlLiWf4hy Rudolf and Sarkar @InorgChem #iridium #mesoionic #imines #catalysis
Design of a Mesoionic Janus-type Dicarbene | Journal of the American Chemical Society @NUSingapore #Mesoionic #Janus #Dicarbene https://t.co/AuW9QYd149
#NHCs #NHeterocyclicCarbenes Ghadwal group published an interesting review on #mesoionic carbenes & #anionic #dicarbenes. Powerful ligand design to enhance the reactivity of classical imidazol-2-ylidenes! @pengcheng_gao @Ghadwal_Group @angew_chem
https://t.co/xW8xD9oXo4
A Mesoionic Carbene–Pyridine Bidentate Ligand That Improves Stability in Electrocatalytic CO2 Reduction by a Molecular Manganese Catalyst https://t.co/8yEWF9FocY Carr, @wpiers1, and co-workers @InorgChem #manganese #mesoionic #carbene_pyridine #electrocatalysis #CO2 #reduction
#NHCs #NHeterocyclicCarbenes Sarkar group published a review on 1,2,3-#triazolylidene #mesoionic carbenes. #Ligands, #electronics, #complexes & photophysical properties. Applications in main group chemistry & catalysis! @Tongliang_Zhou @SarkarAg @JACS_Au
https://t.co/Kn4TY2DvYs
#NHCs #NHeterocyclicCarbenes Matsubara group et al reported #CNC #pincer #mesoionic #carbene nickel(II) complexes. #triazolylidenes Good reactivity in #Suzuki cross-coupling #Bulky N-wingtip substituents are more effective. @SouravSekharBe2 @EurJIC
https://t.co/pvWtWikJKi
#NHCs #NHeterocyclicCarbenes Mendoza-Espinosa group published a review on #multi-#nuclear #mesoionic 1,2,3-#triazolylidene-metal complexes. Strong s-donors. #Click synthesis. Enhanced reactivity! @YaweiZhu77 @mendoza_group @DaltonTrans
https://t.co/uyOL79bB20
Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry https://t.co/BY3a5uZdAh Munz, Hohloch, and co-workers @InorgChem #vanadium #mesoionic #NHC #lowtohighvalent #DFT
#NHCs #NHeterocyclicCarbenes Albrecht lab reported evaluation of stability of #metal-#NHC bonds using #thiones as probes. #imidazolylidenes & #mesoionic #triazolylidenes. Kinetic lability of Ir(III), Rh(III) & Ni(II). @wenchao558 @albrecht_lab @ChemCommun
https://t.co/XCGAnfxtzX
#NHCs #NHeterocyclicCarbenes Severin et al reported computational analysis of 71 #mesoionic #imidazolylidenes. Variation of #aryl & #heteroaryl substituents at C2. Better σ-#donors & π-#acceptors than classical NHCs. @pengcheng_gao @kay_severin @ChemEurJ
https://t.co/y3lnx36VLl
Now with page numbers - very stimulating collaboration with our floor mates @RahamanM_Chem from the Broekmann labs and congratulations to Simone for showing that Ni can convert CO2 to FA @green_rsc #mesoionic #carbenes https://t.co/yTzYmybWpE
#NHCs #NHeterocyclicCarbenes Albrecht group reported #oxo-#functionalized #mesoionic-#NHC #nickel complexes for selective #electrocatalytic reduction of #CO2. C,O-#bidentate chelation. CO2 to #formate conversion. @Shiyi37699738 @albrecht_lab @green_rsc
DOI: 10.1039/d1gc00388g
#NHCs #NHeterocyclicCarbenes Sarkar's group reported #mesoionic carbene based #metallocage. Mesoionic carbenes. #MICs. Ag(I)-NHCs. #Methylene-bridged bis-#triazoliums. Analogue of #tetracyanoethylene. @MdMahbu98665337 @SarkarAg @ChemicalScience
DOI: 10.1039/d0sc06957d
Radicals based on mesoionic carbenes of the triazolylidene-type make their debut. We present design principles based on selenium and gold aducts to stabilize such radicals @ChemEurJ . #carbene #radicals @EPR_ESR #electrochemistry #mesoionic
https://t.co/tptFeIRFnr
#NHCs #NHeterocyclicCarbenes Sarkar group investigated electronic properties of #triazolylidene #mesoionic carbenes. Weak yet variable π-#acceptance. #TEP comparable to IMesMe. #MIC #selones #Ir-CO #triazolylidenes @Tongliang_Zhou @SarkarAg @Orgmet_ACS
https://t.co/Gg1dAbGQfQ
#NHCs #NHeterocyclicCarbenes Ghadwal group reported #Ni-catalyzed 1,2-aryl #migration of #mesoionic carbenes (iMICs). #Super-iMICs show good activity in C‒N #crosscoupling. #mesoionic carbenes #stereoelectronics @pengcheng_gao @Ghadwal_Group @angew_chem
https://t.co/7uDxL00xs2
#NHCs #NHeterocyclicCarbenes Bera's group reported a #proton-responsive annulated #mesoionic carbene #iridium complex and its application in #reductive #amination of aldehydes and transfer #hydrogenation of imines. @Tongliang_Zhou @Orgmet_ACS @berachm
https://t.co/LXmGNrdc9S
#NHCs #NHeterocyclicCarbenes Bera’s group reports #pyridyl #mesoionic #carbene #palladium(II) complex in #Wacker-type oxidation of terminal olefins. #electronic asymmetry #different σ- and π-#bonding characteristics @pengcheng_gao @ACSCatalysis @berachm
https://t.co/cLjKns3AZN
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