The final list of oral and poster presenters has been determined. Please check the presenter list and the tentative program for OMCOS-22. https://t.co/0TslJ5sEG0
The paper provides an in-depth yet concise review of our recent research on developing the seven-membered dialkoxysilane Si(pan) unit and its use in the substructure of various active species, which enables intriguing transformations of silicon-containing molecules. Enjoy it!
We are thrilled to announce the publication of our new Account in @synlett_journal about our research on the seven-membered dialkoxysilane, Si(pan)! https://t.co/hVPyPkaaQF
#OMCOS22 abstract submission deadline has been EXTENDED to May 24 (Sat)! Still time to submit your research for consideration among 400 poster presentations (42 selected for oral). Students & early-career researchers especially encouraged to participate. https://t.co/BCRb4pfZrV
OMCOS-22 abstract submission deadline is approaching (May 13)! Submit your research for consideration among 400 poster presentations (42 selected for oral). Students & early-career researchers especially encouraged to participate. https://t.co/fAaWTVFIR3 #OMCOS22
Kenshiro, @jshimok, and @yorimitsu_lab disclose a new method for silylation of an organic chloride via the formation of Si(pan)-potassium species. • https://t.co/iul8kuQp9g
The cyclic structure of Si(pan) restricts the potential structure of intermediates, facilitating the computational rationale of the whole reaction process. I hope anyone interested in silicon chemistry, mechanisms, and the synthesis of silylated molecules to enjoy this article.
I am pleased to present our latest study, which has been published in Angew. Chem. Int. Ed. In this study, we demonstrated that a disilane of Si(pan), seven-membered dialkoxysilane, and KOtBu mediate the silylation of aryl and alkyl chlorides. https://t.co/MWl3PVnd84
We sought to expand our understanding of the underlying mechanism. We confirmed the crystals of the intermediate silylpotassium thanks to 18-C-6 and the intrinsic ability of Si(pan) to effectively facilitate crystal formation.