My latest work is now published in @J_A_C_S !
We show how axial ligands influence the mechanism and selectivity of dicobalt-catalyzed O₂ reduction to H₂O or H₂O₂ through detailed spectroscopic and kinetic analysis.
#JACS#Catalysis
https://t.co/ZH2uNAGfwg
Incredibly proud to share our group's latest publication, now out in JACS! Thanks to MSc student Luise and collaborator Robert for making this happen.
https://t.co/T8HVxDWK5s
Congratulations Alina and Yusuff! It was so much fun to work with the @MiricaGroup on applying pulsed EPR to characterize organometallic intermediates on our favorite metal! https://t.co/U9CRTdsGAd
Congrats @PintuGh90578115, @smaitichem on their recent @J_A_C_S article showcasing anti-Markovnikov alkene hydrocarboxylation via CO₂ radical anion utilising a synergestic triple catalytic cycle!
Special thanks to our collaborator @DavideAudisio.
Link ⤵️
https://t.co/IRPSKjBdjI
It's an immensely proud and joyful moment for India as we celebrate winning gold medals in both the Open and Women's sections at the Chess Olympiad! Just a few years ago, @vishy64theking made history as the first Indian World Champion, holding the title for five years. Now, a new generation of talented players is emerging, each with the potential to become the next World Champion. Last year, both teams earned bronze, and this time they’ve claimed double gold. The future of Indian chess shines brighter than ever!
Megan’s paper is now online in Accounts! We tried our best to describe how to make catalysts out of chromium @ACSPublications@ChemistryUVA @uvavpr
https://t.co/tWxRRsz0zl
Mechanism of Electrochemical Proton Reduction Catalyzed by a Cobalt Tetraaza Schiff Base Macrocyclic Complex: Ligand Protonation and/or Influence of the Chloro Ligand | ACS Catalysis https://t.co/GGULoAuUr0
@DCMGrenoble
Our first paper on ACS models is live in @J_A_C_S. NHCs being as trusty as ever, we find that Ni1+ can bind CO and convert it into thioesters, just like the enzyme! Excited to see where this new project goes with @ra_musgrave @RoesslerGroup https://t.co/VfQfpypbTB
Congrats to Maike and Maria for carefully designing expts required to accomplish this work!
Exploring the Influence of H-Bonding and Ligand Constraints on Thiolate Ligated Non-Heme Iron Mediated Dioxygen Activation - now published in Chemical Science https://t.co/zltaeTEh2y
Unisyscat groups now report an unusual S=1 Fe(III)-O2-Cu(II) complex that reproduces the blue color and 750 cm-1 rRaman band of the as-isolated CcO. A pure non-heme approach provides vital insights to CcO reactivity. @acsJACS
https://t.co/N9bwubMYi6
@HumboldtChem@UniSysCat