Now out in Structure and Bonding (@SpringerNature).
One periodic logic across the group: σ-donation Al(I) > Ga(I) > In(I), with Tl(I) restricted to Z-type/metallophilic behavior.
➡️ https://t.co/p0D2JBsoYL
Chapter accepted! Group 13 Metals as L-type Ligands for Transition Metals for Structure and Bonding @SpringerNature vol. Transition Metal–Main Group Heterobimetallics ed. by @CamposGroup. Kudos @hellen_videa & M. A. Fuentes @geqo_rseq@CIQSO_UHU
Preprint: https://t.co/9TFRaeptry
Bravo! We are very excited to see this gallyl–gold chemistry for ammonia activation out.
Well done @hellen_videa, fantastic tandem work with @keelan542, and a great collaboration with @TobiKraemer
🔥Hot Paper in @angew_chem!
Counterion control unlocks nucleophilic gallyl anions, enabling unsupported Ga–Au chemistry for NH₃ activation
Work led by @hellen_videa in our group, in collaboration with @TobiKraemer and @keelan542@geqo_rseq@CIQSO_UHU
https://t.co/c3crAgBP5T
Chapter accepted! Group 13 Metals as L-type Ligands for Transition Metals for Structure and Bonding @SpringerNature vol. Transition Metal–Main Group Heterobimetallics ed. by @CamposGroup. Kudos @hellen_videa & M. A. Fuentes @geqo_rseq@CIQSO_UHU
Preprint: https://t.co/9TFRaeptry
BREAKING NEWS
The Royal Swedish Academy of Sciences has decided to award the 2025 #NobelPrize in Chemistry to Susumu Kitagawa, Richard Robson and Omar M. Yaghi “for the development of metal–organic frameworks.”
🔗Al & Ga go mechanical!
First mechanically interlocked metal–organic cages from main-group metals Al₆L₄ and Ga₆L₄ with reversible assembly in H₂O, kudos to @nachoizqdo for leading this work #decker
OA: https://t.co/ooUD4oDj6w
@CIQSO_UHU@geqo_rseq@geqor@GroupMartinez
Article from the "Supramolecular Organometallic and Main Group Chemistry Lab"
"Cooperative Reversible Assembly in Triply Interlocked Al6L4 and Ga6L4 Cages"
Chem. Sci., 2025 @RoySocChem
https://t.co/Y4H5mtN8G1
I've had a fantastic time visiting CIQSO in Huelva and giving a seminar (first for @tcddublin). Impressed with the institute, its researchers and the great work done there. Thanks Antonio and Maria for your generous hospitality! It's been a pleasure. @CIQSO_UHU@GroupMartinez
Tobias Krämer @TobiKraemer from Trinity College Dublin @tcddublin delivering an outstanding talk on Al(I) chemistry at the @CIQSO_UHU seminar series! Thanks Tobi for the insightful discussions and a good dose of fun!
CIQSO SEMINAR📢📢📢🎓🎓🎓
Title "Electronic Structure and Reactivity of Low-Valent Aluminium Compound”
Speaker:
Prof. Tobias Krämer
School of Chemistry
Trinity College Dublin
(Ireland)
March 6, 12:30
CIQSO Auditorium, Robert H. Grubbs Building