Harder-Research

[Harder-Research @harder_research]

Our new Harder Group Poster 2024
(hopefully now without mistakes...)

[Harder-Research @harder_research]

@SchelterGroup Congrats Eric,
that a nice feather on your hat!

[Harder-Research @harder_research]

STRONTIUM POWER: Although this series follows the octet rule, only neutral Ph3N is stable. Ph3B is very resistant to double reduction. Only Ar3B.- radical anions are known. However, it had to surrender to strontium. @angew_chem https://t.co/9SZ2Fap58D

[Harder-Research @harder_research]

OXIDATION STATE CONFUSION in look-alike Mg-Ca and Mg-Yb complexes. Formally Mg(0)-Ca(II)/Yb(II) but energy decomposition analysis EDA-NOCV suggests a combination of neutral (BDI*)Mg(I)/(Am*)Yb(I) radicals @ChemicalScience https://t.co/JFqJVX1RNS

[Harder-Research @harder_research]

SOLVENT-FREE ALKALINE-EARTH ALKYLS are very useful precursors in group 2 chemistry. Here we report facile syntheses of highly reactive Ca, Sr and Ba complexes, partially by ball-mill methods. @Orgmet_ACS https://t.co/GwLpH6vhfJ

[Harder-Research @harder_research]

Even microwave conditions did not lead to deprotonation of the arm. But the tridentate nacnac ligand stabilizes heteroleptic Sr complexes which are normally very much prone to Schlenk equilibria. @ZAAC_Journal https://t.co/9MKtcURAb3

[Harder-Research @harder_research]

Very nice story Ajay👍

[Main Group Chemistry @ IISERTVM @MainTvm]

A single-source precursor for mixed fuel gases!🔥Meet Mg[(CH₃)ZnH₃]—a hydride-rich organometallic that releases a mixture of #Hydrogen & #methane, at just 80 °C. A fundamental discovery that could open up practical applications! #energy #chemistry
https://t.co/pcsEO8GPYa

[Erli Lu Group @erli_lu]

Ca Metal + Mechanochemistry -> Teflon degradation into CaF2, out in @J_A_C_S
now: https://t.co/l2GN5LfAHF

Again, a nice piece of work with the @DominikJKubicki, @r_armstrong_lab and @TomislavFriscic groups.

@UoBChemistry @ChemistryNCL

[Erli Lu Group @erli_lu]

Organosodium mediated ortho-selective C(sp2)-H metalation. Check it out in @ChemicalScience: https://t.co/8TkefqTccU
Another nice paper with the @r_armstrong_lab, @jad5888 groups. Well done @Matthew_Lowe11.

@UoBChemistry @ChemistryNCL

[Jamie Hicks @HicksChem]

Check out Becca's latest paper on hydrogenation of C–C multiple bonds with simple calcium salts. No precious metal catalyst, no H2 gas, and no solvent - just CaH2, Ca(OH)2 and a ball mill!

https://t.co/Y2NztEuHnJ

[Sharanappa Nembenna @SharanNembenna]

Have a look our just published article on biguanidinate boron-chalcogen multiple bonded species https://t.co/iRhHn6l3Ft Heartiest Congratulations to Sagrika and Dimple @niser_official @DaltonTrans Thanks to Reviewers for their suggestions

[Jones Research Group @Jones_Research]

This one from Dat and Corinna has been accepted @DaltonTrans. Check it out. #ozchem @AFOSR @arc_gov_au https://t.co/gG8zZektTI

[Kyle Pearce @KyleGPearce]

Our latest cooperative Ca/Zn venture: ether activation and alkyl migration. Some fun labelling experiments and stellar DFT by @Morales_Chem and @clairemcmullin disclosed within (@angew_chem).

https://t.co/oVnUvFvtrD

[KretschmerLab @KretschmerLab]

There is a new aluminium(I) compound out there. Simon Schreiner went down in Group 13 and got a new member of the Fluind family. Great start of a joint project with Jens Beckman. Reactivity studies are underway - stay tuned!
Thanks to DFG for funding.

https://t.co/AA8pEuObya

[Roel Bienenmann @BienenmannR]

Excited to share our new paper on a Nickel Aluminium dihydride complex which exhibits cooperative reactivity in catalysis! Want to know how? Check it out now: https://t.co/KLek9mWOv7

#MyFirstChemSci #OpenAccess @ChemicalScience @EvaHeviaGroup @universitybern

[Reece Lister-Roberts @ReeceL_R]

Our latest work using nitrogen photocatalysis for nitrous oxide reduction is now online at @angew_chem : https://t.co/goJk2wF4tt

This was a fun one for me learning about photochemistry and applying it to greenhouse gas reduction, a problem I care deeply about.

[Jones Research Group @Jones_Research]

Matt’s (@EvansInorganic) joint Monash/Flinders crossover work on super-bulky [NNN]3- ligands, and Al complexes thereof, is out @ChemEurJ. It is open access, so check it out.
#ozchem @AFOSR @arc_gov_au
https://t.co/CWjM1KnYBL

[Jones Research Group @Jones_Research]

Nice to see the recent resurgence in indium hydride chemistry after a ca. 20 year hiatus. #ozchem
https://t.co/cX1J9JkSrv

[Israel Fernández Group @isra_group]

Check out our just published work in Advanced Science @Wiley_Chemistry with @BreherGroup on a novel concept about The Preparatory (Anti)Bonding Character of Molecular Orbitals. Great work by @JonasOliverW @UCM_OrgChem https://t.co/GoOgKALx0P

[Jacobi vW lab @TeamJacobivW]

Erwin Weiss 100 @unihh
We celebrated the 100th birthday of Erwin Weiss, organometallic pioneer & former @ChemieUHH colleague.
Great talks by @yorimitsu_lab , @harder_research, & Marina Uzelac. Thanks! OrgMetChem is alive and kicking! @LisaVondung @crystalmooc @johannes_walker

[Jones Research Group @Jones_Research]

Dat (@ng_tiendat) and Corinna's (@C_Czernetzki) joint study on ligand and metal specific outcomes of K reductions of flexible, extremely bulky NON-group 2 metal (inc. Be) complexes has appeared as a pre-print @ChemRxiv. https://t.co/WxfAVpe74L #ozchem @AFOSR @arc_gov_au