Catalyzing Singlet Fission by Transition Metals: Second versus Third Row Effects
By Rik Tykwinski & Dirk Guldi @UniFAU@UAlberta
🔓 Open access in Precision Chemistry 👉 https://t.co/7RElHs2bh3
Joe @JC_Goodall running some serious air-sensitive mass spec, using our bespoke glove box interface, as made by the excellent Stu in our @ChemistryatYork workshops (impressive O2 ppm levels as well)
Together with @HLAGroupOx we made an antiaromatic carbon allotrope. It is a molecule called cyclo[16]carbon. And it even is doubly-antiaromatic. What that means and how that was done, you can read in Nature: https://t.co/tZ4pS5Svj2
Validation of a New Methodology to Create Oral Drugs beyond the Rule of 5 for Intracellular Tough Targets | Journal of the American Chemical Society #Lipinski#Ruleof5#OrallyAvailable#Drugs#Protein#KRAS https://t.co/7QfIzG2R6o
Heteroleptic Fe(III) complexes with the BNPAPh2O- ligand framework reported by @VishalYadavChem @Goldberg_Lab display radical reactivity, resulting in transfer selectivity of OH > N3 > NCS > NCO > Cl when reacting with trityl carbon radicals. Check it out: https://t.co/vjDHnXMDYI
From this week's covers: Single─Not Double─3D-Aromaticity in an Oxidized Closo Icosahedral Dodecaiodo-Dodecaborate Cluster.
Read the full article here ➡️ https://t.co/ErvS49wDrH
📈 Read one of our most read open access articles, 'Excited-State (Anti)Aromaticity Explains Why Azulene Disobeys Kasha’s Rule'.
Read the full article here ➡️ https://t.co/LbbobCNXnO
The future looks bright for titanium. Barker et al. @FurmanChemistry developed design strategies for luminescent titanocenes leading to a complex showing visible red LMCT emission in RT solution with a lifetime of 180 ns. Please have a look: https://t.co/FMrp24Bxdz
Diiron + NO produces nitrite as well!? 🤯Check out our latest paper on @J_A_C_S . Oxidation of NO to nitrite with a {FeNO}6/{FeNO}7 intermediate. Congratulations to Anna @a_poptic, Jeff @JeffKlingKlang, and Sam @OSU_CBC
https://t.co/SKSPKSQABo
Our new report in @J_A_C_S shows how carefully selected organic reactions can access an array of functional polyethylenes from a common intermediate. These materials have enhanced properties and improved methods for recovery! https://t.co/5HiFfqzZXe @GroupHelms@MessersmithLab