Redox Studies of the Scandium Metallocene (C5H2tBu3)2ScII Lead to a Terminal Side-On (N═N)2– Complex: [(C5H2tBu3)2ScIII(η2-N2)]− | Journal of the American Chemical Society @UCIPhysSci@UCIrvine@UCIChemistry https://t.co/3XDQ19mQeh
An in crystallo Wolff rearrangement has been reported by @schneider_lab in @J_A_C_S.
Crystal matrix isolation enabled characterization of a Wolff metallocarbene intermediate (a component of CSD entry CUMVIT).
🔗 https://t.co/c8ahlCWBL4
#FeaturedStructureFriday
Room-Temperature H2 Splitting and N2-Hydrogenation Induced by a Neutral LuII Complex | Journal of the American Chemical Society @IP_Paris_@CNRS@Univ_Toulouse https://t.co/mo81coyLMi
The CCDC team are saddened to learn that George Sheldrick has passed away.
His impact in #crystallography was immense; from the SHELX software used globally, to teaching, structures, journals, and more.
More by the ECA here: https://t.co/yonuwTx438
We finish X with a scientific firework! Very proud of a brilliant team to finally publish our work on C(sp3)-atom transfer @ScienceMagazine ! Thanks to @ERC_Research https://t.co/0iM98jSM8k
Excited to share our latest work in JACS @JACS https://t.co/X11wOst2cQ.
@schneider_lab We report the Wolff rearrangement of a metalated diazoester and confirm the crystal structure of transient carbonylcarbene by photocrystallography.