Out now in @JOC_OL! We found that silyl ketene acetals and electron deficient nitrostyrenes react via an unexpected radical pathway to form anti-Michael products.
@iquimicaunam#JOrgChem#OrganicChemistry#OpenAccess
https://t.co/9xN6K3l62R
We’re excited to share our latest paper in @Synthesis_1969! A metal-free radical cascade enables indole dearomatization → spiroindolines. Xanthate chemistry from esters, nitriles, ketones & lactones → enamides in 1 pot! @LuisDemetrio_M@mario_garciacst@iquimicaunam
An elegant approach to furan-fused naphthopyrones and application to the synthesis of (+)-lasionectrin and its C12-epimer is reported by the group of Sartillo-Piscil (@fergotico). Please have a look: https://t.co/9LZFAcEkjk
Delighted to share our new work on "Oxy- and Chloroarylation Pathways in Gold-Mediated Cyclization of 2-Aminoaryl-3-arylpropargyl-benzenesulfonamides", now online in @ChemEurJ.
@iquimicaunam@LatinXChem
@julia_ur1@LatinXChem@GroupGamba@OrgBiomolChem@EurJOC Nice work! Do you have any thoughts about why is ethanol considerably less effective than methanol? Do you think the pressure generated or the ammonium salt solubility might be playing a role?
@r________n31h9c @LatinXChem@EurJOC A really nice work!
How did you know there was a configuration retention after the diazotization/bromination step in Scheme 2? Was it a complete retention?