Top Tweets for #allenes
Our new review in Coord. Chem. Rev.🚀@ElsevierChem
Allene hydroboration: mechanisms, selectivity & scope.
Great work from our lab by Aleksandra Szymańska @phu_chem, @SzylingJ with collaboration with Shaozhong Ge (@NUSingapore)
https://t.co/kh72I54bmy
#hydroboration, #allenes

🎁HBT Henning Hopf, who turns 85 today. He is an eminent #hydrocarbon chemist who made major contributions to #alkenes and alkines, #allenes and cumulenes, as well as cyclophanes and dendralenes, and he wrote “Classics in Hydrocarbon Synthesis”, published 25 years ago by @Wiley_VCH.
Reading and writing, translating and editing are a most important part of his scientific life—he is a true “man of letters”. Currently, he is a member of the Advisory Board of “Lives in Chemistry” https://t.co/DBaasuUtTX, a series of so far 15 autobiographies of great chemists.
Hopf studied chemistry at the Univ. of Göttingen @uniGoettingen and the Univ. of Wisconsin-Madison @UWMadison, where he received his PhD in 1967 for work with Harlan L. Goering. His academic career started with a habilitation in Karlsruhe (today KIT) in 1972; professorships at the Univ. of Würzburg @Uni_WUE (1975–1978) and at the Univ. of Braunschweig @tuBraunschweig followed. Hopf served as President of the German Chemical Society (GDCh) @GDCh_aktuell in 2004/2005, and he was instrumental in unveiling the role of chemical societies and their representatives in the Nazi era, which earned him the prestigious Primo Levi Award of the GDCh and the Italian Chemical Society (SCI) @SocChimIta.
#OrganicChemistry #PrimoLevi #KITKarlsruhe

🔬Site-Selective #Gold-#Catalyzed Alkylation of α-Aminotropones with #Allenes (Bertuzzi/Bandini)
@M_BANDINI_GROUP #catalysis #metalcatalisys @JOC_OL
https://t.co/kDqS5isynw
Synthesis of Chiral Endocyclic Allenes and Alkynes via Pd-Catalyzed Asymmetric Higher-Order Dipolar Cycloaddition | Journal of the American Chemical Society @TotalSyntheses #Allenes #Alkynes #Pd #Catalysis #Asymmetric #DipolarCycloaddition https://t.co/Fagqkdajmn
Copper-Catalyzed sp2 C–H Arylation and Alkynylation of Allenes via Hydrogen Atom Abstraction | Journal of the American Chemical Society @TotalSyntheses #Cu #Csp2 #Arylation #Alkynylation #Allenes #Hatom #Abtraction https://t.co/NWUdqkeMU4
Photoexcited Palladium-Catalyzed Deracemization of Allenes | Journal of the American Chemical Society @TotalSyntheses #Photoexcited #Pd #Catalysis #Deracemization #Allenes https://t.co/lRbazZMPxy
Reductive Dimerization of Alkenes and Allenes Enabled by Photochemically Activated Zinc–Zinc Bonded Compounds | Journal of the American Chemical Society @UT3PaulSabatier #Dimerization #Alkenes #Allenes #Photochemical #Zn @TotalSyntheses https://t.co/sqrc1a0Af4
Enantioselective Synthesis of Allylic Sulfones via Rhodium-Catalyzed Direct Hydrosulfonylation of Allenes & Alkynes | Journal of the American Chemical Society @AponickGroup @UF #Enantioselective #Allylic #Sulfones #Rh #Hydrosulfonylation #Allenes #Alkynes https://t.co/MKMgv08uoB
Ni-Catalyzed Highly Regio-/Enantioselective Semihydrogenation of Racemic Tetrasubstituted Allenes via a Kinetic Resolution Process | Journal of the American Chemical Society @CHNsci #Ni #Catalysis #Enantioselective #Semihydrogenation #Allenes #Resolution https://t.co/1mxam50bUh
Strain-Driven Cascade Converting Benzynes to Alkynylbenzocyclobutenes to Dienynes to Allenes to Benzocyclohexadienones | JACS @UMNChemistry @UMN #CAscade #Strain #Driven #Benzynes #AlkynylCyclobutenes #Dienyne #Allenes #Cyclohexanediones @TotalSyntheses https://t.co/VXbwsSG40x
Enantio- & Diastereodivergent Cyclopropanation of Allenes: Directed Evolution of an Iridium-Containing Cytochrome | Journal of the American Chemical Society @UCBerkeley @HartwigGroup @UCB_Chemistry @BerkeleyLab #Cyclopropanation #Allenes #Ir #Cytochrome https://t.co/4mEhNe4xtx
Stereoselective Synthesis of Densely Substituted [3]Dendralenes via Ru-Catalyzed Dimerization of 1,1-Disubstituted Allenes | Journal of the American Chemical Society @CHNSci @TotalSyntheses #Stereoselective #Dendralenes #Ru #Dimerization #Allenes https://t.co/thEAYWdAo7
Site-Selective sp2 C–H Cyanation of Allenes via Copper-Catalyzed Radical Relay | Journal of the American Chemical Society @CHNSci @TotalSyntheses #SiteSelective #CHFunctionalization #Cyanation #Allenes #Cu #Radical #Relay https://t.co/0lw3ysz5l2
Catalyst-Controlled Annulations of Strained Cyclic Allenes with π-Allylpalladium Complexes @uclachem @UCLA @GargLab @TotalSyntheses #CatalystControlled #Annultions #Strained #Allenes #Pd https://t.co/KWtl9AxPsL
#NHCs #NHeterocyclicCarbenes Check out our review on metal-NHC-catalyzed hydration reactions. Catalytic addition of #water to #alkynes, #allenes & #nitriles! @pengcheng_gao @ELSchemistry
The link below provides free access to the article!
https://t.co/EeTZqtqtn7

#NHCs #NHeterocyclicCarbenes Check out our review on metal-NHC-catalyzed #hydration reactions. Au-NHCs are a powerful tool in the catalytic addition of #water to #alkynes, #allenes & #nitriles! IPrAuCl is the best catalyst! @pengcheng_gao @ELSchemistry
https://t.co/EeTZqtqtn7

#NHCs #NHeterocyclicCarbenes Roglans group reported Rh(I)-NHC catalyzed [2+2+2] cycloaddition of 1,5-bis-#allenes & alkynes. Hemilabile thioether N-Ar wingtip critical for reactivity & excellent trans-diastereoselectivity! @Shiyi37699738 @ACSCatalysis
https://t.co/hJBs8sLvGn
![Szostak_Group's tweet photo. #NHCs #NHeterocyclicCarbenes Roglans group reported Rh(I)-NHC catalyzed [2+2+2] cycloaddition of 1,5-bis-#allenes & alkynes. Hemilabile thioether N-Ar wingtip critical for reactivity & excellent trans-diastereoselectivity! @Shiyi37699738 @ACSCatalysis
https://t.co/hJBs8sLvGn https://t.co/S4NfAcj5eT](https://pbs.twimg.com/media/Fp2d-3-XsAE2myk.png)
Substrate Facilitating Roles in Rare-Earth-Catalyzed C–H Alkenylation of Pyridines with Allenes: Mechanism and Origins of Regio- and Stereoselectivity https://t.co/BnBfZsGEDJ Luo and co-workers @InorgChem #scandium #CH_alkenylation #pyridines #allenes #selectivity #DFT #MWB46

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![synlett_journal's tweet photo. Breaking barriers in #bicyclo[2.2.2]octadiene synthesis!💥 Serafino and Maestri @unipr have compiled an impressive overview of recent advancements in their synthesis, showcasing the collective efforts of researchers in this exciting field 🌟
#Allenes
👉 https://t.co/tXMnZN5RkD https://t.co/MNWUxF2zWh](https://pbs.twimg.com/media/GVVUPFrXkAAeNfb.png)


