Estic llegint molts twitts a X d'investigadors i investigadores molt jóvens molt frustrats per no haver aconseguit un contracte Juan de la Cierva i/o Ramón y Cajal i he pensat fer aquest fil 🧵👇
Our new paper is out in Org. Lett.! 🎉
We synthesized a rigid and configurationally stable figure-eight macrocycle via the inner-bond-cleavage approach.
“Inner-Bond Cleavage of Sterically Congested Dibenzo[g,p]chrysene to a Rigid Figure-Eight Macrocycle”
https://t.co/cnQKxbKsfR
Our latest paper has appeared on @J_A_C_S#ASAP ! We report a unique Kekulé-type molecule that unexpectedly features a triplet ground state. This leads to the manifestation of ground-state Baird aromaticity in a 16π system. https://t.co/nep6CwEsWx
Our account on molecular nanocarbons with diverse connectivity and topologies via Bi(OTf)3-mediated benzannulation is now published in Acc Chem Res: https://t.co/4vRMd2xWeK
Enantiospecific Magnetoconductance Asymmetry in a Racemic Conglomerate Driven by Surface-Assisted Symmetry Breaking | Journal of the American Chemical Society https://t.co/gGPLp8NW2U
We demonstrate the toposelective on-surface synthesis of curved π-extended oligomers using bowl-shaped SubPcs as precursors!
Our work (@labella_jorge, @TTorresGroup) is now published in @ChemicalScience together with J. Lobo-Checa and @JonasBjoerk.
https://t.co/3bHYwYVQXN
Our latest manuscript is now live on ChemRxiv!
Title: An X‑Shaped Chiral Non‑Fullerene n-Type Semiconductor: Ap-plication in Perovskite Solar Cells and Chirality‑Induced Spin Selectivity
https://t.co/EDdAzrd1By
Infinite Stacking of Antiaromatic Ni(II) Norcorroles Formed in a Porous Hydrogen-Bonded Organic Framework | Journal of the American Chemical Society https://t.co/cxNmFrGgWo
MOPEG gel appeared in @J_A_C_S !! The MOP gel, covalently linked by PEG, affords free coordination sites that recognize guest molecules, and changes its size and mechanical properties. Great work by our former postdoc, Tomoki Tateishi @t_tateishi_ !!
https://t.co/4N0txAGiXw
Probing Bowl-to-Bowl Inversion in Enantiopure Subphthalocyanines: Cofacial SN2 vs SN1 Pathways at a Tetracoordinate Boron Center ( @J_A_C_S ): https://t.co/H9ULsWdtHB ( @TTorresGroup , @labella_jorge ).
Excited to share our new paper, now published in @J_A_C_S!
Using SubPcs, we uncover dual-pathway axial ligand exchange at chiral tetracoordinate boron, involving bowl-to-bowl inversion.
Huge thanks to @labella_jorge and @TTorresGroup for their guidance!
https://t.co/Iuz6eWWDza
Boron in MOFs: Fabrication of corrugated halogen 2D metal-organic frameworks by means of F···Au coordination (@labella_jorge): https://t.co/XMrPyXhzO9 (@Chem_CP).
On-surface chemistry is known for challenging conventional reactivity, and here’s a striking example.
We show that confining bowl-shaped aromatics on surfaces allows fluorine atoms to engage in robust coordination chemistry! Now out now in @Chem_CP!👇https://t.co/8a6hnI6InS
New paper in Nature Chemistry: We find that on-surface radical ring-opening polymerization of [6]CPP on Cu(111), produces near micrometer-long poly(para-phenylene) (PPP) chains — far beyond typical polymer lengths obtained by On-Surface Synthesis.
🔗 https://t.co/sBINdQGeRT 1/4