A new study reveals the local structure and electronic state of liquid TcH(CO)5: carbonyl ligands dominate its electronic structure, while the strong Tc–H bond explains its unusual resistance to CO substitution.
@JPhysChem
https://t.co/z0ItAlQHlq
Am(III)/Eu(III) extraction kinetics using microfluidics, computer vision for automated droplet analysis, and molecular dynamics to probe solvent effects on ligand mobility.
A serious paper on polar solvents — with one polar bear joke at the end. 🐻❄️
https://t.co/mfCZzlmWeR
A Case of Macrocyclic N,N′-Diphenyl-Substituted Phenanthrolinediamides: Molecular Dynamics and Eu3+/Am3+ Binding Affinity | Inorganic Chemistry https://t.co/indyqy6ykP Nenajdenko and co-workers @InorgChem#DAPhens#europium#americium#macrocycles
We rigidified DGA - literally. Cyclic diglycolamides with locked amide substituents show unusual extraction behavior: even Am(III)>Eu(III) in some cases. Structure really matters.
https://t.co/eorcEwvASL
We systematically establish L3 and L1-edge XANES fingerprints of rhenium across oxidation states 0 to +7, revealing how ligand donor–acceptor properties and 5d hybridization govern spectral shifts
https://t.co/P1GShVv9x3
Our theoretical and experimental XAS study of neptunium in different oxidation states has been published in Physical Chemistry Chemical Physics.
@PCCP#actinides#XAS
https://t.co/sx2mVVXCuw
Our new work on a highly robust phenanthroline-dicarboxamide extractant enabling efficient Am(III)/Cm(III) separation, validated in counter-current tests with real VVER-1000 raffinate.
@InorgChemFront@mariiaevsiunina@annadkrot
https://t.co/Vm52OLpdtF
New work out by @rcsabya and undergrad co-author Naomi Rehberg! Continuing our interest in actinide-arene and borohydride bonds. https://t.co/OjQjsB0MIf
We are pleased to present our new work in
@JMaterChem
C "Towards Accelerating the Discovery of Efficient Iridium(III) Emitters Using Novel Database and Machine Learning Based Only on Structural Formula" @ML_Chem
https://t.co/73muQm757E
Our comprehensive study on “simple” inorganic compounds - double sulphates of An(III) (U, Np Pu, Am) is out in Inorganic Chemistry @ACSPublications#actinides
https://t.co/6y9pQeb1ec
Solvent Extraction and Coordination Properties of 1,10-Phenanthroline-2,9-dicarboxylic Acid Diamides with Alkyl-Aryl Substituents toward Lanthanides(III) and Americium(III) https://t.co/FARkWh1rDg Evsiunina, Nenajdenko, and co-workers @InorgChem#lanthanides#americium#DAPhen
✨Alpha Emitters and Where to Find Them! ☢️
Are you thinking about working with alpha emitters but unsure where to start? We are happy to share our "Alpha Atlas" − a global map of production centers and suppliers of alpha-particle emitters! 🌎
Link to the full version below👇🏻
Using microfluidic techniques, we have shown the role of proton in the kinetics of Am(III)/Ln(III) extraction by polydentate extractants
@ACSPublications@JPhysChem
https://t.co/BVqAu2uqt3
High extraction separation as a result of ion-pair formations. Find all the details and discussion on different types of stereoisomers in our new article @mariiaevsiunina@pimatveev@ChemEurJ
https://t.co/GvfxMilQrU