Sp3 Methylene CH coupling with heteroaryls has been limited (really annoying for medichemists). With bifunctional pyridone ligands and new mechanism via Pd(II)/Pd(0), we made a big stride: https://t.co/krVnNkj1Y2
❗New ChemRxiv❗A Nitrogen atom insertion strategy into benzimidazoles that lifts a longstanding bottleneck in the synthesis of 1,2,4-triazines. This work highlights the potential of Skeletal Editing as a powerful synthetic tool for accessing rare heterocyclic scaffolds.
Nickel‐Catalyzed 1,2‐Arylalkenylation of Unactivated Alkenes Enabled by a Native Hydroxy Group - Wang - Angewandte Chemie International Edition - Wiley Online Library https://t.co/4TqEwKjpA3
N-Aryl-BIP Ligand-Enabled Iron-Catalyzed Asymmetric Synthesis of β-Amino Free Alcohols from Alkenes | Journal of the American Chemical Society https://t.co/q6FfUW2o33
Happy to share two recent productive collaborative works with Professor Jun (Joelle) Wang at HKBU published in @J_A_C_S and @angew_chem! In the first one, we found that using different acid additives can modulate regioswitching by having different acid binding modes to Ni
A proud milestone for @rr_lab - our first JACS publication! Heartiest congratulations to Chandru, Bincy, Sanjai, Sheryl & Venkadesh for this remarkable achievement and well-deserved success. 👏✨https://t.co/7VrDqGcCUD
@rr_prof@Chemie_iisertvm@tvmiiser
🧪Breaking breakthrough in asymmetric photocatalysis!
#SUSTech researchers developed a novel Relay Energy Transfer photocatalysis paradigm, with findings published in @ScienceMagazine.✨
Read more: https://t.co/KhbzWcqaN7
Our work on deep-red/NIR light-driven Ni-catalyzed C(sp²)–C(sp³) cross-coupling has been published in ACS Catalysis (@ACSPublications). Congrats Kanji and Yusuke! https://t.co/pShlhMynY1
Enantioselective Nickel-Catalyzed Cross-Dehydrogenative Coupling of Aldehydes and Alkenes toward Skipped Enones | Journal of the American Chemical Society https://t.co/IMzwrGOUsA
With a bulky 1,3-diketone ligand, a nickel-catalyzed remote substitution of unprotected alkenyl alcohols with arylboronic acids has been realized, enabling distal C–C bond formation directly from native alcohols. Just out @J_A_C_S | https://t.co/o5c54hNJ98
Excited to share our new publication in @J_A_C_S, wherein formal carbonyl insertion was achieved at the para or ortho position of pyridines, enabling access to 1,4- or 1,2-azepinones, which could be smoothly downstreamed into bicyclic pyrrolidinones. https://t.co/6tJtWm8R3K
🚀Can CO2 radical anion be a reductant for ConPET process?
Here is our recent @ChemRxiv on "Adaptive Photocatalytic Regimes Enabled by CO2•− and ConPET Synergy"
Excellent work done by @SMChem_ & @Shantanu_JUchem 🥂
🔗Read here:👇
https://t.co/6JXt4im2IK
Congrats, Shumpei, Takumi, and Yota! We report "The Synthesis of Tertiary Alkylamines from Alkyl-Substituted Alkenes Using Amine Umpolung Strategy" in J. Am. Chem. Soc. @J_A_C_S https://t.co/fSLVuJpGaI
If you like harnessing carbenes from di-chlorides, you’ll LOVE skeletal editing with tri-chlorides!
Congrats to Bethany, Hojin, Victoria, and our collaborators from Chicago (Ethan & Mark Levin) and California (Anna, Zhang & Dave Olson)!
Open access: https://t.co/XKCX5ba0ry