Was a really cool study with interesting structures. The Ar3P3 are very good P-Transfer agents. Hopefully these NHP systems can provide the ground for more to follow. Thanks to everyone involved.
Iron and rhodium coordination chemistry and catalysis with a chelating bisphosphinidene ligand donating up to eight electrons! Very enjoyable working with @C_HJunghans and @siewert_jan of the @hering_lab on this project! With Braulio Puerta Lombardi, who is not on Twitter. Yet.
@siewert_jan from @likat_rostock is kicking off the afternoon’s session with his talk “Synthesis and coordination of novel chelating Bis(NHC-phosphinidene) ligands”. Some beautiful #phosphorus#chemistry on display at the #19EWPC#3SWPC.
@SharmaaMahendra@RoySocChem@RolandRoesler@hering_lab We didn’t investigated the chemistry towards Lewis Acids. For monodentate NHC-stabilized phosphinidenes it’s known that AlCl3 or BPh3 can extrude the P-unit