C(sp3)−F Bond Activation by Lewis Base‐Boryl Radicals via Concerted Electron‐Fluoride Transfer - Guo - 2025 - Angewandte Chemie International Edition - Wiley Online Library https://t.co/UfXQ65Lh2n
My latest, first-author, pure DFT-calculation paper.
@zsgTHU@angew_chem Congratulations! I am happy to have successfully recommended your outstanding work to our new journal. Hope it could got highly cited!🥳
It’s Novit!! Dicationic tetrylenes [E]²⁺ are fascinating: Lewis acidic, ambiphilic, unstable, and hard to bind to metals. In our new Angew. Chem. Novit paper @angew_chem, we stabilize them and show how they modulate Pt⁰ electrophilicity in catalysis.
https://t.co/4u8U53YBct
Who is the fastest on the catalytic track? 🏁
In our Angew. Chem. Novit cover, Ge, Sn, and Pb dicationic tetrylenes become race cars carrying Pt⁰ catalysts. The trend: Ge²⁺ > Sn²⁺ > Pb²⁺
Cover art meets Z-type ligand chemistry!
https://t.co/4u8U53Z921
Published in #AngewandteChemieNovit: A Review on Functionalizations of C─H and C═C Bonds in Polyolefins Catalyzed by Transition-Metal Complexes by Nicodemo Ciccia & John Hartwig. Read it here: https://t.co/2bRiVES6HO
So sad: 🌻only one month after his 90th birthday, Herbert W. Roesky passed away on December 5. For the numerous contributions of this inorganic chemistry hero, see our birthday post.
@funes_ardoiz and the GRUFOR team at @unirioja (@beatriz_penin@Nil_Sanosa@Diego__Sampedro) report the B_rad and React_B_rad maps - a new tool to understand the intrinsic properties and reactivity of a library of boryl radicals. Check it out! • https://t.co/llzGXSknpH
My recent work studing the reactivity of Lewis base-boyrl radical toward Csp3-F activation. Hoping for a good luck.🙏
C(sp3)-F Bond Activation by Lewis Base-Boryl Radicals via Concerted Electron-Fluoride Transfer | ChemRxiv - https://t.co/eMWLgZh8Ki
We're excited to share our latest publication on recent advances in the chemistry of isolable carbene analogues with group 13–15 elements. - now published @ChemSocRev https://t.co/LkchvpBen2
Our latest paper about the Al-Sm complex and its reactivity is now published online. This is the first example of an aluminum-lanthanide bond.
Alumanyl-Samarium(II): Synthesis, Characterization, and Reactivity Studies https://t.co/aMb9l88d9C
Boryls, Their Compounds and Reactivity: A Structure and Bonding Perspective - now published in Chemical Science @ChemicalScience#MyfirstChemSci
https://t.co/Wlp3Wo1MY4
Hydrobismuthation: Insertion of Unsaturated Hydrocarbons into the Heaviest Main Group Element Bond to Hydrogen | Journal of the American Chemical Society @PPPowerLab@uniofjyvaskyla @UCD #Hydrobismuthation#Alkyne#Bismuth https://t.co/GChoLrUqpy
Happy New Year 2024. Our latest research on a stable singlet carbene with a reversed electronic configuration is now published in @ScienceMagazine. The potential is limitless with this innovative molecule! Congrats @ChaopengHu https://t.co/8z2TcUR2dd
Our paper on the synthesis and reactivity of an Fe(II) complex has just been accepted for publication in the Eur. J. Inorg. Chem., special issue ‘EurJInorg Young Talents’. It’s the start of our series on metals in negative oxidation states. More to come! https://t.co/IJBw8kN4Am