maithili

Grad Student in the Baran Lab

[maithili @maithiliterpene]

@PoshmarkSupport URGENT!!!! It’s been a month tha I bought something on Poshmark and it got sent back to seller as USPS never delivered it !! Refund me my money now or I am going to collect all these ppl who haven’t gotten their money and have a fucking big lawsuit. Don’t test me!!

[maithili @maithiliterpene]

@PoshmarkSupport I bought something from your website however USPS was not able to deliver the item and got sent back to the seller. So I want a refund.

[maithili @maithiliterpene]

@Poshmarkapp I haven’t heard from yall in 1 week. The package got sent back to sender bcoz of a mistake USPS made. So I just want my refund !!

[maithili @maithiliterpene]

@bxzhang9 @TonyJohn07 @BaranLabReads Thanks Benxiang!

[Baran Lab @BaranLabReads]

TEN STEPS TO A MARINE TREASURE: Gram-Scale Synthesis of Bipinnatin J – featuring methods that weren't known ≅3 years ago to forge 3 key C–C bonds... Appearing today in @ChemRxiv (https://t.co/AVocmrW1zJ).

Quick Summary: A concise, scalable total synthesis of (–)-Bipinnatin J is disclosed. Commencing from inexpensive starting materials, this marine diterpenoid was fashioned through a highly convergent synthesis enabled by two Ni-electrocatalytic decarboxylative cross–couplings (DCC) leveraging succinate as an ethylene 2-carbon bridge, a unique halogen dance- Zweifel sequence to rapidly access a trisubstituted furan, a recently disclosed Ni-catalyzed 1,6-conjugate addition, and an asymmetric proton transfer.

Shout out to the team that made it happen: @tonyjohn07 @griffin__barnes @maithiliterpene