Check out team MOFganic's newest entry, out now in @J_A_C_S! Superstar PhD student Yihuan showed that MOFs allow for dosage delivery of simple fluorinated gases, enabling switchable control over borylated vs iodinated product formation in electroreductive radical reactions.
Congrats also to post-doc Jiachen, who pioneered the use of Al-fum for fluorinated gas delivery, undergraduate student Oliver, and our long-time collaborator @jhlee_david (and post-doc Johari in his lab)!
Check out Zoe's work on the reactivity of stabilized carbanions with [redacted gas], now out in @JOC_OL! A fun continuation of our collaboration with @TheLambertLab to study new chemical pathways for [redacted gas] capture!
https://t.co/tm6JyDqW0p
.@AtkinsonCenter announces the Direct Air Capture Database, a new tool that tracks progress of technologies engineered to selectively remove CO2 from ambient air. The project was led by members of @CornellChem's Milner Group (@RunOfThePhill)
Cornell Chem's Dr. Youn Jue (Eunice) Bae is part of the team that won funding from the inaugural Scialog Award. More info in the following link!
https://t.co/eVejnCWdCD
Congratulations to @CornellChem professor Youn Jue (Eunice) Bae! She is a member of a team that’s won funding from the inaugural Scialog Award focused on Quantum Matter and Information, from @RCSA1.
@ybae0221
https://t.co/fi8spaTHgP
First, check out Emily's work on using MOFs to safely handle sulfuryl fluoride, an ideal reagent for late-stage fluorosulfurylation to access S-F electrophiles for SuFEx!
https://t.co/T8cdYxFn1n
The Up and Coming Perspective gives opportunities to outstanding early-career researchers from across the materials chemistry community. This Collection showcases contributions from our Up and Coming authors, published in the journal between 2023 & 2025.
https://t.co/HXPPRrdaHd
Caging the Chlorine Radical: Chemoselective Photocatalytic C(sp3)–H Functionalization Enabled by Terminal Cu–Cl Sites in a Metal–Organic Framework | Journal of the American Chemical Society @Cornell https://t.co/GKzjX6af7l
Caging the Chlorine Radical: Chemoselective Photocatalytic C(sp3)–H Functionalization Enabled by Terminal Cu–Cl Sites in a Metal–Organic Framework https://t.co/nb8NNZYuX1
Congrats to all of the co-authors, including 2nd year Katrina, undergrad Sky, and 3rd year Danny, who helped with the scope and other experiments, and group alumnus Tyler who initiated this project building upon his work with Co(III)-Cl MOFs (https://t.co/XMMseAb87e)!
The formation of a less reactive Cl radical species is supported by TD-DFT studies conducted by Akash @KulikGroup and by the observation of a large primary KIE, which is not commonly observed for Cl radical.
Photochemical Fluoroalkylations with Fluorinated Gases Facilitated by a Robust Metal–Organic Framework | Journal of the American Chemical Society https://t.co/DNqFdn20tt